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By Dr. Glenn T. Seaborg (auth.), Norman M. Edelstein, James D. Navratil, Wallace W. Schulz (eds.)

The papers integrated during this quantity have been offered on the symposium on "Americium and Curium Chemistry and know-how" on the overseas Chemical Congress of Pacific Basin Societies in Honolulu, Hawaii, December 16-21, 1984. This symposium venerated 40 years of analysis on americium and curium. for this reason, the papers integrated during this quantity start with ancient views at the discovery of americium and curium and the early characterization in their chemical homes, after which hide a variety of topics, comparable to thermodynamic houses, digital constitution, nuclear reactions, analytic chemistry, excessive strain part transitions, and technological elements. therefore, this quantity is a overview of the chemistry of americium and curium, and offers a viewpoint at the present learn on those components 40 years after their discovery. The editors wish to thank the individuals during this symposium for his or her contributions. it's a excitement to recognize the help of Ms. Barbara Moriguchi in dealing with the executive features of the symposium and of the construction of this quantity. April 2, 1985 Norman M. Edelstein fabrics and Molecular examine department Lawrence Berkeley Laboratory college of California Berkeley, California 94720, U.S.A. James D. Navratil Rockwell overseas Rocky apartments Plant P.O. field 464 Golden, Colorado 80402-0464, U.S.A. Wallace W. Schulz Rockwell Hanford P.O. field 800 Richland, Washington 99352, U.S.A.

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Additional info for Americium and Curium Chemistry and Technology: Papers from a Symposium given at the 1984 International Chemical Congress of Pacific Basin Societies, Honolulu, HI, December 16–27, 1984

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J. Low Temp. Phys. 1978, 30, 561. , J .. Low Temp. Phys. 1980, 41, 397. , Solid State Cornm. 1975, 17, 713. , J. Nucl. Mat. 1972/73, 45, 73. , J. Less-Cornmon Metals 1984, 100, 153. , Dufour, C. , J. Less-Cornmon Metals, in press. , J. Phys. F: Metal Phys. 1985, 15, L29. -40th anniversary of the discovery of Am and Cm, Honolulu, HI, Dec. 19, 1984. , Phys. Rev. Lett. 1984, 52, 1834. , to be published, Jahrestagung Kerntechnik 85, Mey 7-9 1985, Munchen. , Radiochim. Acta 1984, 36, 69. , pers. cornmunication-,-1984.

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Speotrophotometry,methods of solubility, e1eotromigration, solvent extraotion, ion exchange and others have been used for this purpose. The oomposition of simple and complex americium and ourium oompounds, isolated from solutions has been also studied by different methods. The oomplex formation with inorganio ligands, suoh as perchlorate (1), ohloride (1,8), nitrate (9,10), thiooyanate (11), sulfate (9), carbonate (1), phosphate (12,13), as well as trtmetaphosphate (14) has been studied. Amerioium (III) and ourium {III) hydroxides are preoipitated by ammonium hydroxide and alkali (15) as pink gelatinous oompounds.

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