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By Gary S. Silverman, Philip E. Rakita

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9. 1). 60 sulfur burning furnace \ . :: iiiii: ;' ' J boiler and I dry 700 K, SO2, 02, N2 gas to catalytic ~ S02+1~02 superheater ried air ~ SO3 oxidationand H2SO4making --350 K strong sulfuric acid ---~-_E~-j,-jxl iv v v T Y i filtered f packedbed'I AIR DEHYDRATION moist air ~ , . _I'~'~" ~'~'1 --3 volume% ="-_-" / H o gl slightly H20-diluted sulfuric acid Fig. 1. Dehydration of sulfur combustion air in a sulfur buming acid plant. The dried air contains---50 milligrams of H20(g) per Nm 3 of gas.

Com Sulfur, 290, Outokumpu (2004) Sulphuric Acid Plants (Sulphur Combustion Section). Brochure distributed at Sulphur 2004 conference, Barcelona, October 24-27, 2004. com Outokumpu (2005) Latest Developments in Sulfur Burning Sulfuric Acid Plants. Brochure distributed at 29th Annual Clearwater Conference (AIChE), Clearwater, Florida, June 3 and 4, 2005 (also presented as paper by Bartlett, C. com Roensch, L. F. D. F. (2005) Steam and boiler water treatment technologies for the modem sulfuric acid plant, paper distributed at 29 th Annual Clearwater Conference (AIChE), Clearwater, Florida, June 3 and 4, 2005.

I I water + dust + condensed vapors Fig. 2. Dehydration of metallurgical and spent acid decomposition furnace offgas. Dehydration is done after (i) H20(g) has been condensed by gas cooling and (ii) aqueous mist has been removed by electrostatic precipitation (not shown). The gas leaving dehydration contains -50 milligrams of H20(g) per Nm3 of gas. The acid plant's main blower is situated immediately after dehydration. 1 Objectives The objectives of this chapter are to describe" (a) the HzO(g) contents ofpre-dehydration gases (b) the dehydration process (c) H20(g) contents after dehydration.

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