By Smith L. Holt (Eds.)
content material: Surfactant organization buildings / Stig E. Friberg and Tony Flaim --
Radical pair reactions in micellar answer within the presence and shortage of magnetic fields / Nicholas J. Turro, Jochen Mattay, and Gary F. Lehr --
Light-induced electron move reactions of metalloporphyrins and polypyridyl ruthenium complexes in equipped assemblies / D.G. Whitten, R.H. Schmehl, T.K. Foreman, J. Bonilha, and W.M. Sobol --
elements of man-made photosynthesis : the position of strength gradients in selling cost separation within the presence of surfactant vesicles / Mohammad S. Tunuli and Janos H. Fendler --
regulate of photosensitized electron move reactions in prepared interfacial structures : vesicles, water-in-oil microemulsions, and colloidal silicon dioxide debris / Itamar Willner, Colja Laane, John W. Otvos, and Melvin Calvin --
Photochemistry on colloidal silica recommendations / J. Wheeler and J.K. Thomas --
effective water cleavage via obvious gentle in colloidal options of bifunctional redox catalysts / Michael Grätzel --
using cationic surfactants in electrochemistry and catalysis on platinum / Thomas C. Franklin, Maurice Iwunze, and Stephen Gipson --
Reactions of long-chain acidato complexes of transition metals in micelles and microemulsions / G. Mattney Cole, Jr. --
Chemical reactions in water-in-oil microemulsions / Alvoro Gonzalez, John Murphy, and Smith L. Holt --
Inorganic reactions in microemulsions / R.A. Mackay, N.S. Dixit, and R. Agarwal --
The hydrolysis of chlorophyll a in detergentless microemulsion media : an preliminary learn within the improvement of a kinetic version for the geologic transmetalation reactions of porphyrins present in petroleum / David ok. Lavallee, Euphemia Huggins, and Shelley Lee --
Reactions on sturdy potassium permanganate surfaces / Fredric M. Menger --
Photochemical experiences of zeolites / Steven L. Suib, Ovidiu G. Bordeianu, Kerry C. McMahon, and Dimitrios Psaras.
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And Fischer, H. Helv. Chim. Acta, 1974, 57, 2011. 16. ; Grieser, F. K. J. Am. Chem. Soc. 1979, 101, 279. RECEIVED July 2, 1981. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1982. 3 L i g h t - I n d u c e d E l e c t r o n Transfer Reactions of M e t a l l o p o r p h y r i n s and P o l y p y r i d y l Ruthenium Complexes i n O r g a n i z e d Assemblies D. G. WHITTEN, R. H. SCHMEHL T K FOREMAN J. BONILHA, and W. M. SOBO The University of North Carolina at Chapel Hill, Department of Chemistry, Chapel Hill, NC 27514 We have prepared and studied a number of surfactant, hydrophobic and water soluble luminescent metal complexes.
73 0 Cu(II)/l Table i l . ; ACS Symposium Series; American Chemical Society: Washington, DC, 1982. 2. TURRO E T AL. Radical Pair Reactions in Micellar Solution 25 separated to a d i s t a n c e where the exchange i n t e r a c t i o n of the un p a i r e d e l e c t r o n s i s n e g l i g i b l e . At t h i s p o i n t , the s i n g l e t (S) and t r i p l e t (T) energies are e s s e n t i a l l y degenerate and ISC w i t h i n the r a d i c a l p a i r can occur. In homogeneous s o l u t i o n the random movement of the r a d i c a l fragments most o f t e n leads to i r r e v e r s i b l e s e p a r a t i o n of the p a i r , ® and we t h e r e f o r e expect most of the products to a r i s e from u n c o r r e l a t e d f r e e r a d i c a l s .
Chem. Soc. 1980, 102, 4383. 5. J. and Mattay, J. J. Am. Chem. , in press. 6. G. Prog. NMR Spectr. 1973, 9, 145. (b) Kaptein, R. Adv. Free Rad. Chem. 1975, 5, 381. 7. G. T. Ind. Chim. Belge, 1971, 36 1087. L. Russ. Chem. Rev. 1976, 45, 761. 8. ; Ronis Phys. 1980, 73 9. ; Fischer, H. and Paul, H. , Vol. 9, Part b, SpringerVerlag, New York 1977. 10. ; Acc. Chem. Res. 1980, 13, 369. 11. U. J. Am. Chem. Soc. 1977, 99, 4447. K. H. J. Am. Chem. Soc. 1970, 92, 6077. F. J. Tetrahedron, in press. 12. J. and Kraeutler, B.