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By Alfred H. Wachter

Bargains a accomplished therapy of floor chemistry and its functions to chemical engineering, biology, and drugs. specializes in the chmical and actual constitution of oil-water interfaces and membrane surfaces. info interfacial potentials, ion solvation, and electrostatic instabilities in double layers.

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Anal. Chem. 1:73 (1970). J. Koryta, P. Vanysek, and M Brezina. J. Electroanal. Chem. 75:211 (1977). Z. Koczorowski. J. Electroanal. Chem. 127:11 (1981). Z. Koczorowski and G. Geblewicz. J. Electroanal. Chem. 152:55 (1983). G. Geblewicz and Z. Koczorowski. J. Electroanal. Chem. 158:37 (1983). H. H. Girault and D. Schiffrin. Electrochim. Acta 31:1341 (1986). A. G. Volkov. Langmuir 12:3315 (1996). Y. Cheng and D. J. Schiffrin. J. Electroanal. Chem. 429:37 (1997). T. Wandlowski, V. Marecek, and Z. Samec.

23. 24. 25. 26. 27. 28. 29. 30. 31. 32. 33. 34. P. Vanysek, Lecture Notes in Electrochemistry, vol. 39, Springer-Verlag, New York, 1985, pp. 1–106. J. Koryta. Electrochim. Acta 32:419 (1987). Z. Koczorowski, in The Interface Structure and Electrochemical Processes at the Boundary Between Two Immiscible Liquids (V. E. ), Springer-Verlag, Berlin–Heidelberg, 1987, pp. 143–178. L. I. Boguslavsky and A. G. Volkov, in The Interface Structure and Electrochemical Processes at the Boundary Between Two Immiscible Liquids (V.

INTRODUCTION Much attention has been directed since olden times towards ion solvation, which is a key concept for understanding various chemical processes with electrolyte solutions. In 1920, a theoretical equation of ion solvation energy (ÁG0s ) was first proposed by Born [1], who considered the ion as a hard sphere of a given radius (r) immersed in a continuous medium of constant permittivity (), and then defined ÁG0s as the electrostatic energy for charging the ion up to ze (z, the charge number of the ion; e, the elementary charge):   N z2 e2 1 1À ÁG0s ðBornÞ ¼ À A ð1Þ  80 r where NA is the Avogadro constant, and 0 the permittivity of vacuum.

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