Download NMR: Tomography, Diffusometry, Relaxometry by Rainer Kimmich PDF

By Rainer Kimmich

Tomography, diffusometry and relaxometry are fields in keeping with universal actual ideas. The mixed use of such innovations offers synergistic perception into physicochemical fabric homes of an item. the trouble which rookies to the sector face is to perform and to use theoretical formalisms from diversified resources whereas nonetheless studying the rules of NMR and whereas being already engaged in NMR learn. So the author's ambition is a treatise that provides effortless and easy accessibility for the reader to any implied subject of curiosity. He has exerted himself to facilitate the comprehension of NMR rules by means of broad cross-referencing one of the sections and chapters.

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Extra info for NMR: Tomography, Diffusometry, Relaxometry

Example text

A subsequent pulse ofthe same length but with reversed phase then rephases the rotating-frame coherences so that an "echo" appears in the sense of an alignment of the total magnetization along the z axis. In terms of NMR signals, any misadjustment of the dephasing and rephasing intervals leads to a detectable FID after the two pulses, whereas the rotary echo per se is not accompanied by any signal. The rotary echo may be called the rotating-frame analogue of the gradient echo described in the preceding section (compare Fig.

The basic phenomenon behind Hahn echoes is "Larmor precession" about the external magnetic field. The rotating-frame equivalent is "nutation" about the effective field. The first rotating-frame experiment which we draw attention to is the generation of rotary echoes [463]. The quantization direction in the rotating frame is given by the effective field instead of that of the external field Bo (see Sect. 8). , the Bo gradients, in the formation of Hahn echoes is therefore taken over by gradients of the amplitude of the rotating RF field (Bl gradients).

33) represents dipolar order. As we are dealing with spin systems comprising only two coupling partners, there are no "passive" spins, multiple-quantum coherences do not evolve due to dipolar coupling, and neither does the dipolar order term. 35) 8This implies zero- and double-quantum coherences (see Chap. 51). Note that doublequantum coherences (two quanta hw) are to be distinguished from "overtone coherences" (one quantum h2w) [47). The latter transitions contribute in a radiationless way to spin-lattice relaxation (see Chap.

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